Alekseev, Vadim A. and van der Burgt, Peter J.M. and McCaffrey, John G.
(2012)
Luminescence of Ion-Pair States of Halogens in Liquid
Perfluorocarbons.
Journal of Physical Chemistry A, 116.
pp. 1333-1336.
ISSN 1089-5639
Abstract
The I2(D′−A′) luminescence in liquid C7F16, C8F18, C9F20, and
C12F26 has been observed following irradiation with visible (within the I2 X →
B band region) and UV (λ < 300 nm) lasers. The band is shifted by ∼2000
cm−1 to the red relative to the gas phase and is significantly broader (fwhm ≈
3000 cm−1 vs 500 cm−1 in the gas phase). Two-color excitation of other
halogens in CnF2n+2 solvents revealed similarly shifted and strongly broadened
D′−A′ bands of Br2, IBr, and BrCl. The stability of the ion-pair states of
halogens in room temperature liquids opens new experimental opportunities
for condensed phase studies and may be of applied interest considering the
increasing industrial applications of perfluorocarbons.
| Item Type: |
Article
|
| Keywords: |
Luminescence; Ion-Pair States; Halogens; Liquid
Perfluorocarbons; |
| Academic Unit: |
Faculty of Science and Engineering > Experimental Physics |
| Item ID: |
4950 |
| Identification Number: |
https://doi.org/10.1021/jp210973p |
| Depositing User: |
Dr Peter van der Burgt
|
| Date Deposited: |
13 May 2014 11:30 |
| Journal or Publication Title: |
Journal of Physical Chemistry A |
| Publisher: |
American Chemical Society |
| Refereed: |
Yes |
| URI: |
|
| Use Licence: |
This item is available under a Creative Commons Attribution Non Commercial Share Alike Licence (CC BY-NC-SA). Details of this licence are available
here |
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